I don't think it's a good idea to wear leather boots in the rain.
Leather is an organic material, and it absorbs water. Because leather is porous, it also acts like a sponge, which means that the more water you put on it, the more of it will soak up.
The more water that gets into your boots, the less breathable they become. Your feet will get wet and sweatier and you'll be uncomfortable walking around in wet leather shoes or boots. You might also get blisters if your feet are constantly rubbing against each other while you walk.
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